In an associated crop, maize-stylosanthes (Zea mays L. and Stylosanthes guianensis Sw.) in bands and relay, the yield and nutritional value was estimated: protein, neutral detergent fiber (NDF), acid detergent fiber (ADF) and ash, of the S. guianensis biomass, with or without nitrogenous fertilization. A factorial arrangement nested in a completely random block design with four treatments for the legume was used: T1) in band with fertilization 100N-60P-60K; T2) in band with fertilization 00N-60P-60K; T3) in relay with fertilization 100N-60P-60K and T4) in relay with fertilization 00N-60P-60K, and four repetitions. The yield and nutritional value of the aerial maize biomass was also estimated. The crop in relay showed higher production (p0.05) of legume DMS (6,702 kg ha1) than the mixed crop in band (3,264 kg ha1), independently of the dose of fertilization applied. The protein content both in relay and in band was statistically better (p0.05) with full fertilization (NPK): 12.77 % versus 9.35 %, however, the NDF, ADF and the ashes were not statistically different. The maize yield was 12.98 t ha1 of DM and 65.30 t ha1 of green matter.